Anmol Chemicals is the pioneer manufacturers of Sodium Citrate , Pharmaceutical Excipients Fragrance & Flavor chemicals in India. We offer Halal and Kosher Sodium Citrate made in an ISO9001:2008, ISO22000:2005 (FSSC22000) and cGMP certified facility. Our group has several manufacturing facilities spread across the world, supported by toll manufacturers and representatives in UAE, Europe, Africa, USA, China and has several associated manufacturing facilities spread across India. All the Information on Physics, Chemistry, Applications, Uses and Technology on Manufacture of Sodium Citrate is in these pages.
The units have one or more of the certifications like FDA GMP, ISO 9001, ISO 22000, HACCP, REACH, Kosher & Halal

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Sodium Citrate Anhydrous and Dihydrate SDS GHS, MSDS Sheet

Specifications of Sodium Citrate

Sodium Citrate SDS GHS, MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Citnatin, Citreme, Citrosoedine, Citrosodna, Natrocitral; Trisodium citrate dihydrate; 1,2,3-Propanetricarboxylic acid, 2-hydroxy-trisodium salt dihydrate, Citric acid trisodium salt dihydrate.
CAS No.
: anhydrous 68-04-2; CAS: dihydrate 6132-04-3
EINECS: EC Number: 200-675-3
Molecular Weight: anhydrous 258.07; dihydrate 294.10
Chemical Formula: C6H5Na3O7 anhydrous 258.07; C6H5Na3O7-2H2O dihydrate 294.10
Recommended use
: Industrial Manufacturing

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Labeling according to GHS & Regulation (EC) No 1272/2008


GHS Label Elements
NONE

Signal Word: None

Hazards not otherwise classified (HNOC):
May cause mild skin irritation.
May causes mild eye irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

3. Composition/Information on Ingredients

Ingredient: Sodium Citrate Dihydrate or Sodium Citrate Anhydrous
CAS No.: anhydrous 68-04-2; CAS: dihydrate 6132-04-3
EINECS: EC Number: 200-675-3
Percent: 97 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: To treat symptomatically.

5. Fire Fighting Measures

Flammability of the Product: The product is not reported as combustible. It may ignite at high temperature.
Auto-Ignition Temperature: NA.
Flash Points: NA.
Flammable Limits: NA.
Products of Combustion: It emits toxic oxides of carbon and organic fumes when heated to decomposition.
Explosion: Slightly explosive in presence of heat.
Fire Extinguishing Media
: Water spray. Use means suitable for extinguishing surrounding fire. Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information
 In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating through the sanitary system.

7. Handling and Storage

Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Sodium citrate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage or contact with oxidizing material and combustible substances.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Sodium citrate is white crystals or powder or granules.
Odor: None
Solubility: Readily soluble in water
pH: 7.5-9 at 1% solution at 25 C (77F)
Density: 1.7 gm/cc
Molecular Weight: anhydrous 258.07; dihydrate 294.10
Molecular Formula: C6H5Na3O7 anhydrous 258.07; C6H5Na3O7-2H2O dihydrate 294.10
% Volatiles by volume @ 21C (70F)
: -
Boiling Point: -C
Melting Point: -C

10. Stability and Reactivity

Stability: Sodium citrate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic oxides of carbon along with organic fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents and heat.
Conditions to Avoid
: Moisture, Heat, Incompatibles.

11. Toxicological Information

Sodium Citrate Dihydrate: LD50 oral rat 6730 mg/kg
Carcinogenic Effects: Not a reported carcinogen by IARC NTP ACGIH OSHA.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

12. Ecological Information

EC50: 96h 18000 - 32000 mg/L (Chlorella vulgaris, Fresh Water Algae) for CAS No.: 68-04-2
LC50: 96h 18000-32000mg/L (Poecilia reticulata Fish) for CAS No.: 68-04-2
Biodegradability: -
BOD5 and COD: Not available.
Environmental Fate: No information found. The product itself and its products of degradation are not toxic.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. Small amounts of this material may be suitable for sanitary sewer or trash disposal.

14. Transport Information

DOT (USA) & ADR/RID: Not Regulated.
IMDG: Not Regulated.
IATA: Not Regulated.

15. Regulatory Information

USA:
OSHA Hazards
: Not a known hazard.
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
Section 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: None.
TSCA: The Anhydrous Sodium Citrate is listed.
Health & Safety Reporting List: None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs: None of the chemicals in this material have an RQ.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
California Prop 65:
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Massachusetts Right To Know Components: Not listed.
Pennsylvania Right To Know Components: Trisodium citrate
CAS-No.: 6132-04-3
New Jersey Right To Know Components: Trisodium citrate, CAS-No.: 6132-04-3
WGK (Water Danger/Protection): CAS-No.: 6132-04-3

Canada: Canadian WHMIS Classifications: Not controlled.
CAS-No.: 6132-04-3 is not listed on Canada's DSL List.
CAS-No.: 6132-04-3 is not listed on Canada's Ingredient Disclosure List.

EINECS: EC Number: 200-675-3
Sodium citrate is an EU permitted Food Additive (E 332).

Section 16 - Additional Information

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Sodium Citrate Manufacturers:

Anmol Chemicals
S-8, SARIFA MANSION, 2ND FLANK ROAD, CHINCHBUNDER, MUMBAI 400009, INDIA
TEL: (OFFICE) 91-22-23770100, 23726950, 23774610, 23723564 - FAX: 91-22-23728264

e-mail: anmolc@mtnl.net.in

Anmol Chemicals

Exports to USA, Canada, UAE, Dubai, South Africa, Tanzania, Kenya, Nigeria, Egypt, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Europe Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Korea, Japan,etc.

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